Polymerization catalyst and method

C - Chemistry – Metallurgy – 08 – F

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252/109, 402/418

C08F 4/64 (2006.01) C08F 10/00 (2006.01)

Patent

CA 1129841

Abstract of the Disclosure A novel olefin polymerization catalyst and method is provided wherein the catalyst is prepared by mixing an alkyl aluminum halide, a dialkyl magnesium compound and a reducible titanium compound of the formula Ti(OR)nX4-n where R is an alkyl group, preferably of 1 - 6 carbon atoms, X is a halogen atom, and n is an integer between 0 and 4, inclusive, in the presence of a solvent and a particulate organic polymer whereby a reaction product is formed on the particles and evaporating the solvent. The reaction product is active in the presence of an organometallic co-catalyst such as alkyl aluminum and alkyl zinc co-catalyst for the polymerization and copolymerization of 1-olefins.

322358

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