Polymeric products

C - Chemistry – Metallurgy – 08 – G

Patent

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402/137, 402/138

C08G 18/58 (2006.01) C08G 59/50 (2006.01) C08G 73/02 (2006.01) C08L 63/00 (2006.01) C08L 75/04 (2006.01) C25D 13/06 (2006.01)

Patent

CA 1105189

ABSTRACT OF THE DISCLOSURE Polymeric products comprising the acidified reaction product of an organic polyepoxide and a polyamine containing at least two tertiary amine groups are disclosed. The polyamine and the organic polyepoxide are reacted with one another under conditions to form an internally ionized, quaternary ammonium salt group-containing polymer which has a high molecular weight, but relatively low equivalent weight. The poly- amine is formed by reacting an organic polyisocyanate with an active hydrogen-containing tertiary amine. The reaction product is acidified to form the quaternary ammonium salt groups. Preparing the polyamine in this manner gives one wide latitude in determining the final structure of the polyamine. In effect, one can "tailor make" the polyamine by appropriate selection of reactants and exert a great measure of control over the properties of the final polymeric product. The preferred polymeric products are non-gelled, water-dispersible and electrodepositable on the cathode.

277165

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