Process for the manufacture of a perfluoralkoxy-propionic...

C - Chemistry – Metallurgy – 07 – D

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260/354.1

C07D 319/12 (2006.01) C07F 9/26 (2006.01) C07F 9/535 (2006.01)

Patent

CA 1049537

PROCESS FOR THE MANUFACTURE OF A PERFLUORALKOXY- PROPIONIC ACID FLUORIDE OF FORMULA C9F16O4 AND FOR THE SIMULTANEOUS MANUFACTURE OF DIFLUORPHOSPHORANES Abstract of the Disclosure : Reaction of hexafluoropropene epoxide with phosphoric acid tris-(dialkylamides) gives the new perfluoro-.alpha.-[3.6-dimethyl- 1.4-dioxanyl-2-oxy]-propionic acid fluoride. By hydrolysis and decarboxylation of the acid in the presence of fluorine perfluoro-2-ethoxy-[3.6-dimethyl-1.4-dioxane] is obtained which can be used as chemically inert lubricant or heat transfer liquid.

231752

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