Oxidation of olefins

Details Oxidation of olefins Oxidation of olefins

C - Chemistry, Metallurgy

07

D

260/372

C07D 303/04 (2006.01) C07D 301/04 (2006.01)

Patent

CA 1110260

ABSTRACT Propylene oxide and other olefinic oxides are synthesised by reacting olefin and oxygen in the presence of a catalytic amount of a complex of the type L2MX2, L2M or L2R where L is a ligand which is resistant to oxidation under the conditions of the process and contains a Group 5b element (preferably phosphorous), M is a Group 8 metal (preferably palladium), X is an acidic anion (preferably chlorine) and R is an olefin (preferably ethylene). Increased yields of olefinic oxide may be obtained by the introduction of hydrogen, preferably together with a catalytic amount of a transition metal salt or transition metal complex. -1 -

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