Process for the production of unsaturated carboxylic acids...

C - Chemistry – Metallurgy – 07 – C

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260/482.7, 260/5

C07C 57/04 (2006.01) C07C 51/353 (2006.01) C07C 67/343 (2006.01) C07C 69/54 (2006.01)

Patent

CA 1224801

ABSTRACT OF THE DISCLOSURE unsaturated carboxylic acids and/or esters thereof are produced by reacting an aldehyde comprising formaldehyde or acetaldehyde with either a saturated carboxylic acid ester or anhydride in the vapour phase in the presence as catalyst of a high silica crystalline aluminosilicate zeolite in which the cation is H+ and/or a transition metal and/or a rare earth metal. In a modification of the process instead of formaldehyde there is used methanol/molecular oxygen and in the catalyst there is included either an oxidative or an oxidative/dehydrogenative component.

451696

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