Process for the preparation of esters of...

Details Process for the preparation of esters of... Process for the preparation of esters of...

C - Chemistry, Metallurgy

07

C

260/482

C07C 67/36 (2006.01) C07C 67/38 (2006.01) C07C 69/533 (2006.01) C07C 69/54 (2006.01)

Patent

CA 1284656

A B S T R A C T PROCESS FOR THE PREPARATION OF ESTERS OF ALPHA-ETHYLENICALLY UNSATURATED ALCOHOLS AND ALPHA-ETHYLENICALLY UNSATURATED CARBOXYLIC ACIDS Process for the preparation of esters of alpha- ethylenically unsaturated alcohols and alpha-ethylenically unsaturated carboxylic acids by reacting an acetylenically unsaturated compound with CO and a ketone containing a group HC-C(=O), using a Pd(II) catalyst, a triphenylphosphine in which the phenyl groups carry an electron-withdrawing substituent and a non-carboxylic protonic acid having a pKa not greater than 1.5.

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