Catalyst and reactions employing same

B - Operations – Transporting – 01 – J

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B01J 27/14 (2006.01) B01J 31/24 (2006.01) C07C 68/06 (2006.01) C07C 69/06 (2006.01)

Patent

CA 1212096

ABSTRACT OF DISCLOSURE A NOVEL CATALYST AND REACTIONS EMPLOYING SAME A novel catalyst comprises (i) an organophosphorus-containing compound, (ii) a compound, which is reactable in the Michael reaction, and contains both (a) a double or triple bond and (b) an electron withdrawing group and (iii) an alcohol or a mixture of an alcohol and a solvent. The novel catalyst may be generated from a novel catalyst precursor. The catalyst may be used to transesterify carboxylic or carbonic acid esters, to produce formate esters from alcohols and carbon monoxide and to produce formamides from amines and carbon monoxide.

453892

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