Process for para selective alkylation of aromatic hydrocarbons

C - Chemistry – Metallurgy – 07 – C

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260/684

C07C 2/66 (2006.01) C07C 2/86 (2006.01) C07C 15/02 (2006.01)

Patent

CA 1232293

PROCESS FOR PARA SELECTIVE ALKYLATION OF AROMATIC HYDROCARBONS ABSTRACT OF THE DISCLOSURE A process for the selective alkylation of monoalkylbenzene into dialkylbenzenes wherein the para isomer of the disubstituted product is present in a concentration greater than in a thermodynamic equilibrium is provided. The method comprises passing the monoalkylbenzene and an alkylating agent capable of methylation, ethylation or propylation through a reaction zone containing an unmodified crystalline silica catalyst of the silicalite type having the monoclinic symmetry.

467775

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