Photoisomerisation of trans-cyclopropane-nitriles

C - Chemistry – Metallurgy – 07 – C

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204/91.19, 260/5

C07C 255/48 (2006.01) B01J 19/12 (2006.01)

Patent

CA 1175065

ABSTRACT Trans-cyclopropane-nitriles of the following general formula:- Image can be converted in to the corresponding cis-form by irradiating the trans-compound with light of wave-length in the range 260- 450 nanometres in the presence of a photo-sensitizer -the triplet state energy of which is in the range 2?0-330 kilojoules per mole.

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