Process for the production of optionally cellular moldings

C - Chemistry – Metallurgy – 08 – G

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403/14, 400/5506

C08G 18/40 (2006.01) C08G 18/63 (2006.01) C08J 9/00 (2006.01) C08K 5/098 (2006.01) C08L 75/00 (2006.01)

Patent

CA 1238450

A PROCESS FOR THE PRODUCTION OF OPTIONALLY CELLULAR MOLDINGS ABSTRACT OF THE DISCLOSURE The present invention is directed to a process for the production of optionally cellular, polyurethane and/or polyurethane-urea moldings having an impervious skin by reacting in a closed mold a reaction mixture containing a) at least one organic polyisocyanate, b) at least one compound which has a molecular weight of about 400 to 12,000 and at least two isocyanate-reactive groups, and c) optionally at least one compound which has a molecular weight of from 32 to 399 and at least two isocyanate-reactive groups, wherein before the reaction takes place a surface- improving additive (e) is added containing el) a liquid and sedimentation-stable polymer disper- sion which is produced by the free radical addition polymeriza- tion or copolymerization of one or more olefini- cally unsaturated monomers in a high molecular weight compound having isocyanate-reactive groups of the type mentioned in (b), and optionally e2) a metal salt of a monocarboxylic acid having at least 8 carbon atoms in the molecule wherein additive (e) is used in a quantity such that about 0.01 to 3 parts by weight of polymer solids of the polymer dispersion (el) and up to about 2 parts by weight of metal salt (e2) are incorporated per 100 parts of component (b).

471172

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