Process for the racemization of optically active aminoacids

C - Chemistry – Metallurgy – 07 – F

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260/534.1, 260/5

C07F 9/50 (2006.01) C07F 9/30 (2006.01)

Patent

CA 1231349

- 1 - Abstract of the Disclosure: The racemization of optically active aminoacids (including their N-acyl derivatives) by heating with carboxylic acids takes place particularly readily with carboxylic acids of low volatility. Only catalytic quantities of acid are needed; it is advantageous to use equimolar quantities or an excess, which serves as a diluent. A reaction mixture from an enzymatic racemate resolution can be heated directly for the purpose of racemization, after separation of the L-aminoacid and the water.

464047

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