Quinacridone pigments, process for their preparation and...

C - Chemistry – Metallurgy – 09 – B

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6/217, 260/275,

C09B 48/00 (2006.01) C09B 67/22 (2006.01) D06P 1/22 (2006.01)

Patent

CA 1336776

A process for the preparation of 2,9-dimethylquinacridone pigments or mixed crystal pigments or mixtures of 2,9-di- methylquinacridone and quinacridones which in the two outer fused benzene rings can be substituted by halogen, alkyl, alkoxy, H2N-CO-, alkyl-NH-CO-or (alkyl)2N-CO groups characterized by the form of their crystalline particles which have an average ratio of length to width of <2:1 and an average particle size of <0.4 µm, by adding to the solution of 2,9-dimethylquinacridone or to the solution of 2,9-dimethylquinacridone together with the quinacridones in acidic solvents and/or during the hydrolysis of these acidic solutions at temperatures from about 0° to about 150°C, and/or before or during the finishing of the corresponding crude quinacridones of the quinacridones mentioned in water or solvent mixtures at temperatures from about 60 to about 200°C, in each case a compound of the general formula (I) Image (I) in an amount of about 1 to 20 % by weight, in which in formula (I) Q is a quinacridone radical which is unsub- stituted or substituted by halogen, alkyl, alkoxy, H2N- CO-, alkyl-NH-CO- or (alkyl)2N-CO- groups, A is a direct bond or a bridge member from the series comprising -O-, -S-, -NR1-, -CO-, -SO2-, -CR2R3-, or arylene, and Y is an -NR4R5 group or the radical of a five-, six- or seven- membered heterocycle which contains one to three hetero atoms and can be substituted by alkyl, alkoxy, hydroxy- phenyl, halogen, -CN, carboxyl, -CO-NRR', -SO2-NRR', hydroxyalkyl or alkylaminoalkyl, R and R' are hydrogen or alkyl, and R1 to R5 are hydrogen and/or alkyl or alkylene , and n is a number from 1 to 4, the pigments themselves thus prepared and their use for the pigmenting of natural or synthetic materials and of lacquer systems.

614210

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