Oxidative coupling of alkylphenols or 1-naphthols catalyzed...

C - Chemistry – Metallurgy – 07 – C

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260/396, 260/616

C07C 39/14 (2006.01) C07C 37/11 (2006.01) C07C 46/08 (2006.01)

Patent

CA 1082208

Abstract of the Disclosure Carbon-carbon coupled self-condensation products obtained by the oxidative coupling of alkylphenols or 1-naphthols are prepared by contacing an aqueous mixture of an alkylphenol or 1-naphthol with oxygen in the presence of sufficient alkaline material to sustain a pH in the range of 8.0-9.5 during the oxidative coupling reaction and a catalyst system comprising a cupric, cobaltous or manganous chelate of an oxime of a keto or aldehyde compound. The mixture may optionally contain a surfactant.

296215

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