Absorption of gases by amine and phosphine complexed mn (ii)

Details Absorption of gases by amine and phosphine complexed mn (ii) Absorption of gases by amine and phosphine complexed mn (ii)

C - Chemistry, Metallurgy

07

F

23/341, 260/166.

C07F 13/00 (2006.01) B01D 53/02 (2006.01) B01D 53/04 (2006.01) B01J 20/00 (2006.01)

Patent

CA 1248942

Abstract of the Disclosure Adsorption of Gases by Amine and Phosphine Complexed Mn(II) and Compounds Amine or diphosphine complexed Mn(II) compounds reversibly adsorb sulfur dioxide and oxygen as well as nitrogen oxides, carbon monoxide, carbon dioxide and lower alkenes. More specifically, these compounds have the following formula: Mn(II)LX2 where X represents F-, Br-, C1-, I-, SCN- or OH-. L is a ligand having the formula N(R1)n; R2-N = N - R3 or Image The metal complexes are used to adsorb gases as a solid adsorbent, suspended on aluminum oxide or dissolved in a non-volatile solvent. The gas can be adsorbed at a low temperature in the range of 30-200°C, and desorbed at a higher temperature in the range of 45-230°C or at a lower pressure.

521597

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