Preparation of alkoxy halides

C - Chemistry – Metallurgy – 07 – C

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260/645.4, 260/6

C07C 43/12 (2006.01) C07C 41/22 (2006.01) C07C 43/225 (2006.01)

Patent

CA 1263412

ABSTRACT Alkyl alkoxy, aryl alkoxy or alkylaryl alkoxy halides are prepared by reacting the corresponding alkoxy alcohol with a halogenating agent, eg., thionyl chloride, in the presence of a soluble compound of a metal of Groups IA and IIA of the Periodic Table as catalyst. In addition to being faster, the catalysed reaction results in an in- creased yield of desired product and a decrease in the tend- ency of the polyoxyalkylene chain to cleave.

497621

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