Graft polymers made with metal/peroxy initiating systems

C - Chemistry – Metallurgy – 08 – F

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Details

400/1334, 400/20

C08F 251/00 (2006.01) C08F 291/08 (2006.01)

Patent

CA 1336460

A graft copolymer is made by grafting, by a free radical reaction mechanism in aqueous solution, water soluble ethylenically unsaturated monomeric material on to a water soluble substrate having hydroxyl groups, and the free radicals are formed on the substrate using an oxidising metal capable of being reduced by the substrate to a lower valency state (for instance cerium) and persulphate or other peroxy compound capable of oxidising the metal back to a higher valency state. The process is preferably conducted as a reverse phase polymerisation process and the invention includes also a novel reverse phase emulsion comprising a dispersion of reverse phase polymer particles of a graft copolymer of carboxymethyl cellulose, dextran or starch with acrylamide and acrylic acid and/or AMPS.

609613

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