Process for the preparation of unsaturated carboxylate esters

C - Chemistry – Metallurgy – 07 – C

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C07C 51/14 (2006.01) C07C 67/38 (2006.01) C07C 69/24 (2006.01)

Patent

CA 1287838

A B S T R A C T PROCESS FOR THE PREPARATION OF UNSATURATED CARBOXYLATE ESTERS Process for the preparation of carboxylate esters of alpha-ethylenically unsaturated alcohols by reacting an ethylenically unsaturated compound with carbon monoxide and an enolizable ketone in the presence of a catalytic system rormed by combining a palladium catalyst, a triarvlphosphine and a protonic acid having a PKa below 1.5, except hvdrohalogenic acids and carboxylic acids.

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