Preparation of resorcinol and substituted resorcinols by...

C - Chemistry – Metallurgy – 07 – C

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C07C 39/08 (2006.01) C07C 37/06 (2006.01) C07C 45/45 (2006.01) C07C 45/81 (2006.01)

Patent

CA 1185619

PREPARATION OF RESORCINOL AND SUBSTITUTED RESORCINOLS BY LIQUID-PHASE DEHYDROGENATION OF 1,3-CYCLIC DIONES DERIVED BY VAPOR-PHASE CYCLIZATION OF DELTA-KETO CARBOXYLIC ACID ESTERS Abstract of the Invention A process is disclosed for making resorcinol and substituted resor- cinols by a first reaction step of vapor phase cyclization of a delta-keto carboxylic acid ester over a carbon catalyst bed to form a 1,3-cyclic dione intermediate. The delta-keto ester is conveyed through the catalyst bed by a vaporized carrier characterized by being liquid at 25°C and having a suffi- ciently high boiling point that the vaporized carrier is easily condensable under ambient conditions. In a second reaction step, a liquid solvent containing the 1,3-cyclic dione intermediate is contacted with a supported noble-metal catalyst to form resorcinol or a substituted resorcinol.

419877

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