Production of tertiary olefins

Details Production of tertiary olefins Production of tertiary olefins

C - Chemistry, Metallurgy

07

C

260/709.9

C07C 1/20 (2006.01) B01J 21/16 (2006.01) B01J 27/06 (2006.01) B01J 37/22 (2006.01) C07C 11/02 (2006.01)

Patent

CA 1261358

ABSTRACT OF THE DISCLOSURE High purity tertiary olefins are obtained in extremely high yields over a sustained period by cracking alkyl tert-alkyl ethers over clay catalysts which have been treated with HF and/or HC1. Preferably temperatures are 100 - 250°C, the surface area of the catalyst is above 40 M2/gm and the cracking step is part of a process for recovering isobutylene or isoamylene from steam cracked streams.

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