Manufacture of alkanols from synthesis gas

C - Chemistry – Metallurgy – 07 – C

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260/638.1

C07C 31/02 (2006.01) C07C 29/157 (2006.01)

Patent

CA 1181100

MANUFACTURE OF ALKANOLS FROM SYNTHESIS GAS (D#75,934-F) ABSTRACT OF THE DISCLOSURE This invention concerns a process of making alkanols and particularly methanol which comprises the steps of contacting a mixture of CO and H2 with a catalyst system comprising a ruthenium-containing compound and a halogen-free rhenium-containing compound or a halogen-free manganese-containing compound dispersed in a low melting quaternary phosphonium base or salt, and heating said resultant reaction mixture under a pressure of 500 psig or greater at a temperature of at least 150°C. -I-

405583

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