Process for the carbonylation of olefins

C - Chemistry – Metallurgy – 07 – C

Patent

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260/495.1, 260/4

C07C 51/567 (2006.01) C07C 51/14 (2006.01) C07C 51/56 (2006.01) C07C 67/38 (2006.01)

Patent

CA 1177845

ABSTRACT A process for the carbonylation of an olefin with carbon monoxide in the presence of water. an alcohol, and/or a carboxylic acid. the reaction being conducted In the presence of an essentially halide-free palladium catalyst and a tri-organophosphine and in the absence of sodium acetate. the tri-organophosphine containing at least one aliphatic carbon atom bound to phosphorus and the molar ratio of the organophosphine to palladium being less than 10:1.

391051

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