Process for forming thermally stable thermotropic liquid...

C - Chemistry – Metallurgy – 08 – G

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402/183, 402/186

C08G 63/06 (2006.01) C08G 63/60 (2006.01) C08G 69/44 (2006.01)

Patent

CA 1214593

IMPROVED PROCESS FOR FORMING THERMALLY STABLE THERMOTROPIC LIQUID CRYSTALLINE POLYESTER OF PREDETERMINED CHAIN LENGTH Abstract of the Disclosure An improved polymerization process is provided for the formation of a polyester which is capable of forming an anisotropic melt phase and which optionally may include amide linkages. An approximately 0.4 to 3 percent molar excess of aromatic dicarboxylic acid monomer (e.g. tereph- thalic acid) and/or an esterified derivative thereof is provided in the polymerization zone during the polymerization reaction. Such monomer imparts dicarboxyaryl units to the interior of the resulting polymer chains and causes the polymer chains to terminate in carboxylic acid end groups and/or an esterified derivative thereof wherein the polymer chains achieve a predetermined average chain length through the depletion of other monomers present in the polymerization zone. The resulting polyester unlike the usual product of the prior art is substantially incapable of additional chain growth upon subsequent heating and accordingly may be relied upon to maintain a substantially constant viscosity during melt processing regardless of the duration of heating.

457517

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