Process for producing ethylene glycol and/or a glycolic acid...

C - Chemistry – Metallurgy – 07 – C

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252/64, 260/488.

C07C 31/20 (2006.01) B01J 23/72 (2006.01) B01J 31/18 (2006.01) C07C 29/136 (2006.01) C07C 29/149 (2006.01) C07C 69/675 (2006.01)

Patent

CA 1206136

ABSTRACT A hydrogenation catalyst composition useful for the hydrogenation of an oxalate diester, said composition being composed of a reduction product of copper- containing silica gel formed by contacting an ammine com- plex of copper with dry silica gel having an average particle diameter of not more than 200 µ; and a process for pro- ducing the aforesaid composition. Using a catalyst composed of the aforesaid composition, ethylene glycol and/or a glycolic acid ester can be produced from an oxalate diester efficiently with high conversions and selectivities and without causing pollution attributed to the use of a chromium-containing catalyst composition.

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