Urethanes which contain perfluoroalkyl groups,...

C - Chemistry – Metallurgy – 07 – C

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260/468, 8/93.23

C07C 271/06 (2006.01) C07C 275/00 (2006.01) C07C 275/62 (2006.01) C08G 18/28 (2006.01) D06M 13/425 (2006.01) D06M 15/576 (2006.01)

Patent

CA 1276164

Abstract of the disclosure: Urethanes which contain perfluoroalkyl groups, epi- chlorohydrin groups and dialcohol radicals, the preparation and use thereof The novel urethanes, in addition to at least one per- fluoroalkyl group, also contain epichlorohydrin groups and dialcohol radicals in the molecule. They are pre- pared by reacting a fluorine-containing alcohol with epichlorohydrin to give the perfluoroalkyl-epichlorohyd- rin adduct, reacting this adduct with a di- or triiso- cyanate to give the perfluoroalkyl-epichlorohydrin-iso- cyanate adduct and by reacting this adduct with a dial- cohol or a monoetherified dialcohol to give the desired urethanes having a perfluoroalkyl group and having epi- chlorohydrin groups and dialcohol radicals, and by reac- ting a suitable urethane compound of this type with a perfluoroalkyl-containing di- or triisocyanate to give the desired urethanes having a plurality of perfluoroal- kyl groups and having epichlorohydrin groups and dialco- holradicals. The novel urethanes are preferably used for the oleophobic and hydrophobic finishing of textiles.

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