Rhodium-catalyzed oxidation process for producing carboxylic...

Details Rhodium-catalyzed oxidation process for producing carboxylic... Rhodium-catalyzed oxidation process for producing carboxylic...

C - Chemistry, Metallurgy

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C07C 53/00 (2006.01) B01J 31/18 (2006.01) C07C 45/50 (2006.01) C07C 51/145 (2006.01) C07C 51/235 (2006.01) C07C 55/02 (2006.01)

Patent

CA 1182127

ABSTRACT OF THE DISCLOSURE A one-step process for forming a carboxylic acid and its anhydride directly from the corresponding olefin which comprises reacting the olefin with carbon monoxide, hydrogen and oxygen in the presence of a rhodium complex catalyst stabilized by a pentavalent Group V ligand, such as a phosphine oxide. Alterna- tively a carboxylic acid can be produced by oxidation of an aldehyde in the presence of a rhodium complex catalyst stabilized by said pentavalent Group V ligand.

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