Process or the preparation of hydrocarbons

C - Chemistry – Metallurgy – 07 – C

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260/678.7

C07C 1/04 (2006.01)

Patent

CA 1140157

A B S T R A C T PROCESS FOR THE PREPARATION OF HYDROCARBONS Hydrocarbons are prepared from H2-poor syngas by contacting it in a first stage with a tri- functional catalyst combination comprising a methanol synthesis or Fischer-Tropsch catalyst, a crystalline silicate with ZSM-5 structure and, possibly a CO-shift catalyst, followed by con- tacting at least the C2- fraction of the first stage product of which the H2/CO molar ratio as such or after adjusting amounts to at least 1.5, in a second stage with a Ni, Co or Ru Fischer-Tropsch catalyst.

354626

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