Process for the production of acylated diketonic compounds

C - Chemistry – Metallurgy – 07 – C

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260/477, 260/542

C07C 49/603 (2006.01) C07C 45/45 (2006.01) C07C 45/54 (2006.01) C07C 205/45 (2006.01) C07C 255/56 (2006.01)

Patent

CA 1317976

PR-7359/7839 PROCESS FOR THE PRODUCTION OF ACYLATED DIKETONIC COMPOUNDS Abstract of the Disclosure An acylated diketonic compound is produced by rearrangement of the corresponding enol ester in the presence of a cyanide source. In one embodiment the cyanide source is employed with a molar excess of a moder- ate base, with respect to the enol ester. In another embodiment, the cyanide source is a stoichiometric amount, with respect to the enol ester, of potassium or lithium cyanide and a catalytic amount of a Crown ether is used.

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