Silicone-polyimide copolymers, condensation vulcanizable...

C - Chemistry – Metallurgy – 07 – F

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400/2005, 400/53

C07F 7/10 (2006.01) C07D 209/76 (2006.01) C07F 7/08 (2006.01) C08G 73/10 (2006.01) C08G 77/04 (2006.01) C08G 77/455 (2006.01) C08G 77/54 (2006.01) C08J 3/24 (2006.01)

Patent

CA 1204760

SILICONE-POLYIMIDE COPOLYMERS CONDENSATION VULCANIZABLE COMPOSITIONS OBTAINED THEREFROM, AND METHODS FOR MAKING ABSTRACT OF THE DISCLOSURE Silicone-polyimide copolymers having terminal silanol or silicon hydride radicals are provided based on the use of a norbornene terminated polyimide. A hydrosilation reaction is employed to introduce silicon-hydrogen into the terminal position of the polyimide having norbornene termination. The resulting hydrosilyl terminated polyimide is reacted with silanol terminated polydiorganosilane in the presence of a catalyst to produce silanol terminated polydiorganosiloxane-polyimide copolymer. Room temperature or low temperature condensation vulcanizable compositions based on the use of such silanol-terminated copolymers provide cured silicone-polyimide copolymers exhibiting improved toughness.

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