Manufacture of aryl esters

C - Chemistry – Metallurgy – 07 – C

Patent

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260/489, 260/485

C07C 67/04 (2006.01) C07C 69/035 (2006.01) C07C 69/353 (2006.01)

Patent

CA 1218671

Abstract of the Disclosure A process is described for the manufacture of aryl esters such as phenyl esters by liquid phase reaction of an aromatic compound such as benzene with molecular oxygen in the presence of a carboxylic acid preferably having 6 or more carbon atoms over a catalyst composed essentially of a compound of palladium, a compound of antimony and a compound of at least one member selected from the group consisting of chromium, cobalt, nickel, manganese, iron, and tin wherein the aromatic compound is added continuously to the reaction and water formed in the reaction is rapidly and continuously removed from the reaction zone.

454171

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