Process for the preparation of hydrocarbons

C - Chemistry – Metallurgy – 07 – C

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260/678.7

C07C 1/04 (2006.01) B01J 23/75 (2006.01) B01J 23/86 (2006.01) B01J 23/89 (2006.01) C07C 1/06 (2006.01)

Patent

CA 1262362

A B S T R A C T PROCESS FOR THE PREPARATION OF HYDROCARBONS A process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen wherein the feed is contacted at elevated temperature and pressure with a catalyst comprising 3-60 pbw cobalt, 0.1-100 pbw zirconium, titanium, chromium and/or ruthenium per 100 pbw of carrier, which catalyst is in the form of a fixed bed and has an external surface area SE and wherein together with the feed a hydrocarbon-containing liquid boiling above 100 °C is passed through the catalyst in a downward direction at such a superficial liquid flow velocity VS at the inlet of the bed that the product Vs x SE is larger than 1.

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