Catalytic process for preparing ethanol

C - Chemistry – Metallurgy – 07 – C

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260/638.1

C07C 31/08 (2006.01) C07C 29/157 (2006.01)

Patent

CA 1230613

ABSTRACT A method for the selective, direct preparation of ethanol which comprises contacting a mixture of carbon monoxide and hydrogen at a temperature of from 100 to 400°C and at a pressure of from 50 to 1000 bars with a catalyst comprising ruthenium and at least one other metal selected from Groups VII and VIII of the Periodic Table and a source of halide ions in a liquid medium comprising an aprotic amide or imide or an aprotic heterocyclic compound containing an -OCO- grouping in the ring.

425971

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