Shape selective acid catalyzed reactions of olefins over...

Details Shape selective acid catalyzed reactions of olefins over... Shape selective acid catalyzed reactions of olefins over...

C - Chemistry, Metallurgy

07

C

260/675.1, 260/6

C07C 2/00 (2006.01) C07C 2/12 (2006.01) C07C 2/54 (2006.01) C07C 2/66 (2006.01) C07C 4/06 (2006.01) C07C 5/00 (2006.01) C07C 5/22 (2006.01) C07C 5/25 (2006.01) C07C 5/41 (2006.01) C07C 17/08 (2006.01) C07C 29/04 (2006.01) C07C 29/38 (2006.01) C07C 31/125 (2006.01)

Patent

CA 1199036

-36- ABSTRACT This invention provides a process for conducting selective acid catalyzed reactions with olefins using as catalysts,the acidic forms of a class of zeolites characterized by a silica to alumina mole ratio of at least 12 and a constraint index of from greater than 2 to 12. Using such zeolites, smaller olefins are preferen- tially reacted when in mixed streams with larger olefins, linear olefins are preferentially reacted when in mixed streams with non-linear olefins, lesser branched olefins are preferentially reacted when in mixed streams with more highly branched olefins and para-disubstituted and/or mono-substituted aromatic olefins will react preferen- tially over ortho- and/or meta-disubstituted or more highly substituted aromatic olefins.

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