Synthesis of hydrophilic phenol ester derivatives

C - Chemistry – Metallurgy – 07 – C

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260/489, 260/465

C07C 69/88 (2006.01) C07C 51/347 (2006.01) C07C 51/567 (2006.01)

Patent

CA 1223881

SYNTHESIS OF HYDROPHILIC PHENOL ESTER DERIVATIVES ABSTRACT A hydrophilic phenol ester derivative, especially a sulphonated or carboxylated phenol ester is prepared by reacting a C6-C18 substituted or unsubstituted aliphatic carboxylic acid with a C2-C3 alkanoic anhydride, and reacting the resultant C6-C18 acid anhydride with a substituted phenol such as an alkali metal phenol sulphonate salt or hydroxybenzene carboxylic acid to give a C6-C18 acyloxy derivative of a substituted benzene. The two stage process may be carried out in the same reaction vessel without the use of solvents. The products are useful as peroxyacid bleach precursors.

437693

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