Metal coated semi-conductor catalysts for hydrogen...

Details Metal coated semi-conductor catalysts for hydrogen... Metal coated semi-conductor catalysts for hydrogen...

C - Chemistry, Metallurgy

01

B

252/52.J, 117/48

C01B 3/06 (2006.01) B01J 19/12 (2006.01) B01J 27/02 (2006.01) B01J 27/04 (2006.01) B01J 27/057 (2006.01) B01J 27/138 (2006.01) C01B 3/04 (2006.01)

Patent

CA 1220163

Metal Coated Semi-conductor catalysts for Hydrogen Production by Photoredox Catalysis Abstract A process is described for the selective production of hydrogen by means of heterogeneous photoredox catalysis, in which mixtures of water and alkali metal sulfites or sulfides, alkaline earth metal sulfites or sulfides or ammonium sulfites or sulfides are reacted under the action of light in a suspension of a cadmium sulfide, cadmium sulfoselenide or titanium dioxide/semiconductor powder which is at least partially coated with Cu, Cr, Ni, Co or a noble metal or mixtures thereof. The catalysts which can be employed in this process (coated semiconductor pow- ders) are in some cases novel.

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