Process for the preparation of unsaturated compounds

C - Chemistry – Metallurgy – 07 – C

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260/703, 260/480

C07C 2/04 (2006.01) C07C 2/36 (2006.01) C07C 11/00 (2006.01) C07C 69/593 (2006.01)

Patent

CA 1269398

A B S T R A C T PROCESS FOR THE PREPARATION OF UNSATURATED COMPOUNDS The dimerization of acrylate esters and of ethene and the codimerization of acrylate esters with C2-4-alkenes or 1,3- butadiene and of 1,3-butadiene with ethene in the presence of: (a) a Pd and/or Ru compound, (b) a compound containing one trivalent N or P atom, and (c) an Ag and/or Cu salt, yields at an increased reaction rate dimers of high linearity, when a quinone is also present.

507699

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