Fused n-phenylsulfonyl-n'-pyrimidinylureas and n-...

C - Chemistry – Metallurgy – 07 – D

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C07D 401/12 (2006.01) A01N 47/36 (2006.01) C07D 217/24 (2006.01) C07D 327/06 (2006.01) C07D 411/12 (2006.01) C07D 521/00 (2006.01)

Patent

CA 1240676

- 1 - Abstract of the Disclosure Fused N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'- triazinylureas Fused N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'- triazinylureas of the general formula Image (I), wherein Z is oxygen or sulfur, E is nitrogen or =CH-, R1 is hydrogen, halogen, nitro, C1-C4alkyl, C1-C4haloalkyl, cyano, or a -X-R5 , -CO-X-R6, -CO-NR7R8, -SO-R9 or -SO2-R10 group, R2 is hydrogen, C1-C4alkyl or C1-C4alkoxy, R3 is C1-C4alkyl C1-C4haloalkyl, C1-C4alkoxy, C1-4haloalkoxy C3-C6cycloalkyl, R4 is hydrogen, halogen, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C2-C4alkoxyalkoxy, C3-C6cycloalkyl or -NR11R12, R5 is C3-C5alkynyl or C1-C4alkyl which is unsubstituted or substituted by halogen or C1-C4-alkoxy, or is C3-C5alkenyl, which is unsubstituted or is substituted by halogen or C1-C4-alkoxy, R6 and R9 are each independently C1-C4alkyl, C1-C4haloalkyl, C2-C4alkoxyalkyl, C3-C5alkenyl, C3-C5alkynyl, phenyl or benzyl, R7 and R8 are each independently hydrogen, C1-C4alkyl, C1-C4halo- alkyl, C2-C4alkoxyalkyl, C3-C5alkenyl, C3-C5alkynyl, phenyl or benzyl, R10 is C1-C4alkyl, C1-C4alkoxy, C1-C4haloalkoxy or -NR13R14, R11 and R12 are each independently hydrogen or C1-C4alkyl, - 2 - R13 and R14 are each independently hydrogen, C1-C4alkyl, C1-C4haloalkyl, C2-C4alkoxyalkyl, C3-C5alkenyl, C3-C5alkynyl, phenyl or benzyl, X is oxygen or sulfur, and A is an unsubstituted or substituted unsaturated bridge of 4 atoms, of the formula -CH=CH-Y-, wherein Y is a bridge member of 2 atoms which is selected from the series consisting of -NH-CO-, -NH-SO2-, -S-CO-, -S-SO2-, -O-CO- or -O-SO2-, and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quarternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties.

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