Process for making vinyl oxazoline drying oil esters

C - Chemistry – Metallurgy – 07 – D

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260/124, 402/403

C07D 263/14 (2006.01) C08F 226/06 (2006.01)

Patent

CA 1181064

ABSTRACT An improved process for preparing a vinyl oxazoline drying oil ester by reacting drying oil fatty acids with tris(hydroxy methyl) amino methane to form an intermediate which is further reacted at about 175-190°C with a formaldehyde/alcohol solution to form the vinyl oxazoline drying oil ester; the improvement used with this process is the use of at least 3 moles of formaldehyde to one mole of inter- mediate and about 1-5% by weight, based on the weight of the intermediate, of methanol and adding after the reaction with formaldehyde about 5-25% by weight, based on the weight of the ester solution, of an alcohol, a ketone or a mixture of an alcohol and a ketone; polymers of this ester and coating compositions of these polymers are also disclosed.

390996

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