Hydrocarbon oxidations catalyzed by iron coordination...

C - Chemistry – Metallurgy – 07 – C

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260/494.3, 260/5

C07C 27/12 (2006.01) B01J 31/18 (2006.01) C07C 29/50 (2006.01) C07C 45/33 (2006.01) C07C 45/34 (2006.01) C07C 45/35 (2006.01) C07C 45/36 (2006.01) C07C 51/215 (2006.01) C07C 51/235 (2006.01) C07C 51/245 (2006.01) C07C 51/25 (2006.01) C07C 51/265 (2006.01)

Patent

CA 1305974

ABSTRACT Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O2 to form such products as alcohols, ketones, and the like selectively in high yields when there is employed as the catalyst a coordination complex containing an iron center and a halogenated ligand having the structure Image where Fe is iron; Image is a ligand; X is a halogen substituent of the ligand; and A is an anion.

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