Process for the preparation of tertiary-butyl hydroperoxide

C - Chemistry – Metallurgy – 07 – C

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260/642.9

C07C 409/04 (2006.01)

Patent

CA 1248972

- 30 - A B S T R A C T A PROCESS FOR THE PREPARATION OF TERTIARY-BUTYL HYDROPEROXIDE In the preparation of tertiary-butyl hydroperoxide by the direct oxidation of isobutane, the production of tertiary-butyl hydroperoxide, expressed as the quantity of the compound prepared per unit of reactor volume per unit of time, is enhanced by conducting the oxidation in a dense, supercritical phase reaction mixture at a temperature in excess of the critical temperature of the mixture, at a pressure in excess of the critical pressure of the mixture.

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