Production of chlorine dioxide in an electrolytic cell

Details Production of chlorine dioxide in an electrolytic cell Production of chlorine dioxide in an electrolytic cell

C - Chemistry, Metallurgy

25

B

204/65

C25B 1/26 (2006.01) C25B 1/46 (2006.01)

Patent

CA 1330964

17 Abstract of the Disclosure Chlorine dioxide is produced electrolytically in the cathode compartment of an electrolytic cell using a three-dimensional high surface-area cathode. The cathode compartment is separated from an anode compartment by a cation-exchange membrane. Sodium chlorate is reacted with hydrogen ions and chloride ions in the cathode compartment and chlorine dioxide is vented from the cathode compartments. Chlorine co- produced with the chlorine dioxide is reduced at the cathode to provide chloride ions for the reaction while electrolytically-produced hydrogen ions are transferred across the membrane from the anode compartment to the cathode compartment to provide hydrogen ions for the reaction.

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