Recovery of molybdenum from spent catalyst solutions from...

C - Chemistry – Metallurgy – 22 – B

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C22B 34/34 (2006.01) B01J 31/40 (2006.01) C01G 39/06 (2006.01) C22B 7/00 (2006.01)

Patent

CA 1181951

RECOVERY OF MOLYBDENUM FROM SPENT CATALYST SOLUTIONS FROM HYDROPEROXIDE EPOXIDATIONS Abstract Of The Disclosure In the process of recovering molybdenum from a spent catalyst solution obtained from a crude reaction product of a molybdenum catalyzed epoxidation of an olefin with an organic hydroperoxide from which crude reaction product epoxide and an alcohol corresponding to the hydroperoxide is removed, the improve- ment comprises removing and recovering dissolved molybdenum as a high molybdenum content solid by subjecting the spent catalyst solution to a liquid-to-liquid extraction with an aqueous extract to form a two phase system, separating the molybdenum aqueous extract and precipitating therefrom a high molybdenum content solid by heating the aqueous extract in the presence of hydrogen sulfide or a water soluble sulfide salt.

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