Process for transhalogenating a halophosphorus compound with...

C - Chemistry – Metallurgy – 07 – F

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C07F 9/14 (2006.01) C07F 9/146 (2006.01) C07F 9/547 (2006.01) C07F 9/6574 (2006.01)

Patent

CA 1317969

PROCESS FOR TRANSHALOGENATING A HALOPHOSPHORUS COMPOUND WITH FLUORIDE Abstract of the Disclosure Phosphorus compounds having at least one chlorine, bromine or iodine bonded directly to phosphorus are trans- halogenated with fluorine by reaction with anhydrous hydrogen fluoride in an inert solvent in a manner such that said anhydrous hydrogen fluoride is added to said phosphorus compound at a rate such that said anhydrous hydrogen fluoride reacts with said phosphorus compound without the accumulation of an amount of unreacted anhy- drous hydrogen fluoride which is sufficient to cause substantial decomposition of the desired fluorophosphorus product.

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