Nitration of organic compounds and organic nitrogen...

Details Nitration of organic compounds and organic nitrogen... Nitration of organic compounds and organic nitrogen...

C - Chemistry, Metallurgy

07

C

260/463.7, 260/6

C07C 201/04 (2006.01) C07C 201/02 (2006.01) C07C 201/08 (2006.01) C07C 203/00 (2006.01) C07C 203/02 (2006.01) C07C 205/02 (2006.01)

Patent

CA 1212953

ABSTRACT Nitration of organic compounds and organic nitrogen compounds produced. Organic nitrogen compounds are formed in the vapour phase by organic radical formation by reaction of an organic compound with hydroxyl radicals derived from the reaction between hydrogen peroxide and nitrogen dioxide and the nitration of the organic radicals, suitably with nitrogen dioxide. The process may be conducted as a single stage process using an excess of nitrogen dioxide over that required for hydroxyl radical formation. The production of hydroxyl radicals is maximised by the use of a catalytic solid surface such as a solid acid or an acidic oxide or mixed oxide. The product may be a mixture of some or all of the nitrite, nitrate and nitro-derivative which may be used as such, e.g. as a fuel additive, as a source of the individual compounds or as a feedstock for a further synthesis.

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