Process for producing hydroxybenzenes

C - Chemistry – Metallurgy – 07 – C

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C07C 37/08 (2006.01) C07C 37/50 (2006.01) C07C 39/02 (2006.01)

Patent

CA 1308122

ABSTRACT Hydroxybenzenes can be produced in high yield through a one-step reaction by subjecting (a) an .alpha., .alpha.-dialkyl-.alpha.- hydroxymethyl group containing benzene and/or (b) a benzene containing both .alpha., .alpha.-dialkyl-.alpha.-hydroxymethyl and .alpha., .alpha.-dialkyl-.alpha.-hydroperoxymethyl groups to reaction in the presence of a nitrile, an acid and hydrogen peroxide. In a preferred mode, the reaction system further contains (c) an .alpha., .alpha.-dialkyl-.alpha.-hydroperoxymethyl group containing benzene.

562470

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