Process for treating h2s containing gas streams

B - Operations – Transporting – 01 – D

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B01D 53/52 (2006.01) B01D 53/50 (2006.01) B01D 53/78 (2006.01)

Patent

CA 2202248

A process for treating non-condensible gas streams containing H2S, and for treating steam containing H2S, is disclosed, the process being characterized by unique division of the non-condensible stream, or of a separated non- condensible H2S-containing stream derived from the steam, with diverse oxidative treatment of the separated portions. The invention is particularly suited to treating the exhaust steam from a steam turbine which utilizes geothermal steam as the working fluid. In a preferred aspect, disposal of sulfur produced as normal byproduct of liquid oxidative steps may be reduced or avoided altogether by reaction of the sulfur with bisulfite and/or sulfite produced in the procedure to produce soluble thiosulfate.

Procédé destiné au traitement de flux de gaz non condensables à base de H¿2?S et au traitement de la vapeur à base de H¿2?S. Le procédé se caractérise par la séparation unique du flux non condensable, ou d'un flux séparé non condensable à base de H¿2?S obtenu à partir de la vapeur, suivi de divers traitements oxydants des parties séparées. L'invention convient particulièrement au traitement de la vapeur d'échappement provenant d'une turbine à vapeur qui utilise de la vapeur géothermique comme fluide de travail. Dans un mode de réalisation préférentiel, il est possible de réduire, voire de supprimer l'utilisation du soufre comme sous-produit des étapes oxydatives liquides en faisant réagir le soufre avec l'hydrogénosulfite et/ou le sulfite obtenu lors de la phase de production d'hyposulfite soluble.

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