Crystalline polyglycolic acid, polyglycolic acid composition...

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 63/88 (2006.01) C08G 63/08 (2006.01) C08G 63/78 (2006.01)

Patent

CA 2710098

The present invention is directed to a process for producing crystalline polyglycolic acid, wherein (a) a difference (Tm - Tc2) between the melting point Tm defined as the maximum point of the endothermic peak attributable to melting of a crystal detected in the course of heating at a heating rate of 10°C/min by means of a differential scanning calorimeter and the crystallization temperature Tc2 defined as the maximum point of the exothermic peak attributable to crystallization detected in the course of cooling from a molten state at a cooling rate of 10°C/min is not lower than 35°C, and (b) the difference (Tc1 - Tg) between the crystallization temperature Tc1 defined as the maximum point of the exothermic peak attributable to crystallization detected in the course of heating an amorphous sheet at a heating rate of 10°C/min by means of a differential scanning calorimeter and the glass transition temperature Tg defined as a temperature at a second-order transition point on a calorimetric curve detected in said course is not lower than 40°C, the process comprising applying heat history to crystalline polyglycolic acid at a temperature between the melting point Tm of the crystalline polyglycolic acid + 38°C and Tm + 100°C for 1 to 100 minutes.

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