Crystalline zeolite zsm-34 and method of preparing the same

C - Chemistry – Metallurgy – 01 – B

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196/36, 402/651,

C01B 39/30 (2006.01) B01J 29/06 (2006.01) B01J 29/50 (2006.01) B01J 29/70 (2006.01) C07C 1/20 (2006.01) C07C 2/12 (2006.01) C07C 4/06 (2006.01) C10G 11/05 (2006.01)

Patent

CA 1097309

ABSTRACT OF THE DISCLOSURE A crystalline zeolite, designated ZSM-34, having the composition as synthesized and in anhydrous form, expressed as mole ratios of oxides as follows: (0.5-1.3)R2O: (0-0.15)Na2O: (0.10-0.50)K2O: Al2O3: XSiO2 where R is the organic nitrogen-containing cation derived from choline [(CH3)3NCH2CH2OH] and X is 8 to 50, said zeolite having an X-ray diffraction pattern, identifying it as a member of the offretite-erionite family and the ability, after calcination at 1000°F for at least a period of time to remove the organic cation, to sorb at least 9.5 weight percent of n-hexane at ambient temperature and a n-hexane pressure of 20mm. Organic compound conversion is carried out in the presence of a catalytically-active form of said zeolite.

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