Polymetalated 1-alkyne compositions

C - Chemistry – Metallurgy – 07 – F

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C07F 1/00 (2006.01) B01J 31/22 (2006.01) C07F 1/02 (2006.01) C08F 4/46 (2006.01) C08F 36/00 (2006.01)

Patent

CA 2051938

Hydrocarbon soluble polymetalated 1-alkene compositions are described, and these compositions may be characterised by the formula Image wherein R is hydrogen, a hydrocarbyl group or R1M, M is an alkali metal, R1 is a divalent oligomeric hydrocarbyl group comprising moieties derived from a conjugated diene, and wherein the total number moieties derived from a conjugated diene in all of the R1 groups in Formula I is from about 2 to about 30. Preferably, the alkali metal is lithium. Hydrocarbon soluble polymetalated 1-alkene catalysts for anionic polymerisations are also described which comprise the reaction product of a 1- alkyne, an organometallic compount R°M, and a 1,3-conjugated dlene wherein R° is a hydrocarbyl group, M is an alkali metal, the mole ratio of conjugated diene to 1- alkyne is at least about 2:1, and the reaction is conducted at a temperatuare of at least about 70°C.

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