Process for the preparation of a catalytic microcomposite...

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252/121, 403/4,

B01J 31/10 (2006.01) C07C 2/66 (2006.01) C07C 5/22 (2006.01) C07C 37/08 (2006.01)

Patent

CA 2293476

The present invention relates to a process for preparing a microcomposite comprising a highly flu-orinated ion-exchange polymer containing pendant sulfonate functional groups, said polymer existing as aggregated particles entrapped within and dispersed throughout a network of silica. Due to their high surface area and acid functionality, these microcomposites possess wide utility as improved solid acid catalysts, particularly in the substitution of aromatic compounds, in the decomposition of hydroperoxides, and in the isomerization of olefins

L'invention concerne un procédé de préparation d'un microcomposite comprenant un polymère échangeur d'ions hautement fluoré, qui contient des groupes fonctionnels sulfonate pendants. Ce polymère se présente sous forme de particules agglomérées piégées et dispersées à l'intérieur d'un réseau de silice. Grâce à leur surface spécifique élevée et à leur fonctionnalité acide, ces microcomposites présentent une large utilité comme catalyseurs acides solides, en particulier dans la substitution de composés aromatiques, dans la décomposition des hydroperoxydes et dans l'isomérisation des oléfines.

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