Process for the preparation of arylamides of heteroaromatic...

Details Process for the preparation of arylamides of heteroaromatic... Process for the preparation of arylamides of heteroaromatic...

C - Chemistry, Metallurgy

07

D

C07D 213/81 (2006.01) C07D 239/34 (2006.01) C07D 241/24 (2006.01) C07D 251/12 (2006.01) C07D 401/12 (2006.01) C07D 403/12 (2006.01) C07D 405/12 (2006.01) C07D 409/12 (2006.01)

Patent

CA 2203592

A process is described for the preparation of arylamides of heteroaromatic carboxylic acids of the formula: (see formula I) in which each A n is nitrogen or CR n (n - 1-5), with the proviso that at least one of the ring members is nitrogen and that two nitrogen atoms are not bonded directly to one another; R1 to R5, if present, independently of one another, are hydrogen, C1-4-alkyl or aryl, one of the substituents R1 to R5 being a group of the formula -OR, in which R is an optionally substituted aromatic or heteroaromatic radical; R6 is hydrogen or C1-4-alkyls and R7 is an optionally substituted aromatic or heteroaromatic radical. The amides are obtained from the corresponding heteroaromatic halogen compounds, the corresponding aromatic amines and carbon monoxide in the presence of a palladium phosphine complex. Compounds of this class are important herbicides.

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